Carothers did not like to interfere with the polymerization process. Carothers was
usually more interested in studying reactions scientifically than using them to make commercial
products. But it worked. Adding acetic acid kept the molecular weight down to usable levels.
Click here to find out how!
2. Labovsky, Joseph. Oral history by John K. Smith, 24 July 1996. Philadelphia: Chemical
Heritage Foundation.
Wesley R. Peterson's nylon
salt and Edgar W. Spanagel's
autoclave
had made it possible to make nylon
polymer
with high average
molecular weights.
Now there was
another problem. Molecular weight was too high! If nylon has a molecular weight much higher
than 20,000, it will be too viscous when melted to be processed into fibers.
Wesley R. Peterson
was wrestling with this problem and with a simple but effective answer. He
added acetic acid to the reaction mixture before
polymerization.
This achieved the desired molecular
weight nylon polymer.
References
1. Hermes, Matthew. Enough for One Lifetime: Wallace Carothers, Inventor of Nylon.
Washington, D.C.: American Chemical Society; Philadelphia: Chemical Heritage Foundation, 1996.